{"id":2715,"date":"2024-05-13T07:47:30","date_gmt":"2024-05-13T05:47:30","guid":{"rendered":"https:\/\/teneochem.pl\/?p=2715"},"modified":"2025-01-31T16:51:14","modified_gmt":"2025-01-31T16:51:14","slug":"dodatek-strukturalny-010","status":"publish","type":"post","link":"https:\/\/teneochem.pl\/index.php\/2024\/05\/13\/dodatek-strukturalny-010\/","title":{"rendered":"Dodatek strukturalny 010"},"content":{"rendered":"\n<p>Podczas konstruowania r\u00f3\u017cnych modyfikacji nanorurek, zdarza\u0142y mi si\u0119 r\u00f3\u017cne pomys\u0142y. Jednym z nich jest konstrukcja zawieraj\u0105ca skondensowane cztery cykle cyklopentadienylowe oraz \u0142\u0105czniki allenowe C=C=C. Te fragmenty, po\u0142\u0105czone ze sob\u0105, tworz\u0105 nanorurk\u0119, kt\u00f3ra dodatkowo zawiera cykle dziewi\u0119ciow\u0119glowe (Orca 5.0.4\/ revPBE\/ def2-TZVP\/ hess-plus)<\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/blog\/allo-novalen-onv-ok-C34H16.sdf' data-backgroundcolor='yellow' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>Poni\u017cszy rysunek pokazuje schemat \u0142\u0105czenia atom\u00f3w obu p\u0142at\u00f3w w programie ChemSketch.:<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"450\" height=\"334\" src=\"http:\/\/teneochem.pl\/wp-content\/uploads\/2024\/05\/allo-novalen-laczenie-platow.jpg\" alt=\"\" class=\"wp-image-2717\" srcset=\"https:\/\/teneochem.pl\/wp-content\/uploads\/2024\/05\/allo-novalen-laczenie-platow.jpg 450w, https:\/\/teneochem.pl\/wp-content\/uploads\/2024\/05\/allo-novalen-laczenie-platow-300x223.jpg 300w\" sizes=\"auto, (max-width: 450px) 100vw, 450px\" \/><\/figure>\n\n\n\n<p>Oznacza to, \u017ce w miejscach skrzyd\u0142owych \u0142\u0105cznikami s\u0105 grupy CH2 a wewn\u0105trz cz\u0105steczki fragmenty allenowe (nale\u017cy utworzy\u0107 dwa wi\u0105zania podw\u00f3jne).<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Podczas konstruowania r\u00f3\u017cnych modyfikacji nanorurek, zdarza\u0142y mi si\u0119 r\u00f3\u017cne pomys\u0142y. Jednym z nich jest konstrukcja zawieraj\u0105ca skondensowane cztery cykle cyklopentadienylowe oraz \u0142\u0105czniki allenowe C=C=C. Te fragmenty, po\u0142\u0105czone ze sob\u0105, tworz\u0105 nanorurk\u0119, kt\u00f3ra dodatkowo zawiera cykle dziewi\u0119ciow\u0119glowe (Orca 5.0.4\/ revPBE\/ def2-TZVP\/ hess-plus) Poni\u017cszy rysunek pokazuje schemat \u0142\u0105czenia atom\u00f3w obu p\u0142at\u00f3w w programie ChemSketch.: Oznacza to, \u017ce [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-2715","post","type-post","status-publish","format-standard","hentry","category-chem"],"_links":{"self":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/posts\/2715","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/comments?post=2715"}],"version-history":[{"count":2,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/posts\/2715\/revisions"}],"predecessor-version":[{"id":3734,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/posts\/2715\/revisions\/3734"}],"wp:attachment":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/media?parent=2715"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/categories?post=2715"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/tags?post=2715"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}