{"id":2397,"date":"2024-04-14T20:22:15","date_gmt":"2024-04-14T18:22:15","guid":{"rendered":"https:\/\/teneochem.pl\/?p=2397"},"modified":"2025-01-31T16:58:43","modified_gmt":"2025-01-31T16:58:43","slug":"dodatek-strukturalny-001","status":"publish","type":"post","link":"https:\/\/teneochem.pl\/index.php\/2024\/04\/14\/dodatek-strukturalny-001\/","title":{"rendered":"Dodatek strukturalny 001"},"content":{"rendered":"\n<p>W\u015br\u00f3d utworzonych struktur pojawi\u0142a si\u0119 taka, kt\u00f3ra jest zasadniczo porz\u0105dn\u0105 nanorurk\u0105 o zdefiniowanym uwodornieniu kilku wi\u0105za\u0144 podw\u00f3jnych. Oznacza to rozaromatyzowanie pier\u015bcieni benzenowych. Nie s\u0105dz\u0119, \u017ceby istnia\u0142a metoda syntezy tak dobrze zdefiniowanych struktur, ale mo\u017ce si\u0119 myl\u0119 (14.04.2024):<\/p>\n\n\n\n<div style=\"height: 400px; width: 400px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/blog\/chinorura5ds0-2-bis-onv-C40H30.sdf' data-backgroundcolor='#9966FF' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>Cz\u0105steczka zosta\u0142a zoptymalizowana za pomoc\u0105 programu Orca 4.2.1 na poziomie DFT (B3LYP\/ def2-SVP). Wszystkie cz\u0119sto\u015bci w hessianie s\u0105 dodatnie.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>W\u015br\u00f3d utworzonych struktur pojawi\u0142a si\u0119 taka, kt\u00f3ra jest zasadniczo porz\u0105dn\u0105 nanorurk\u0105 o zdefiniowanym uwodornieniu kilku wi\u0105za\u0144 podw\u00f3jnych. Oznacza to rozaromatyzowanie pier\u015bcieni benzenowych. Nie s\u0105dz\u0119, \u017ceby istnia\u0142a metoda syntezy tak dobrze zdefiniowanych struktur, ale mo\u017ce si\u0119 myl\u0119 (14.04.2024): Cz\u0105steczka zosta\u0142a zoptymalizowana za pomoc\u0105 programu Orca 4.2.1 na poziomie DFT (B3LYP\/ def2-SVP). Wszystkie cz\u0119sto\u015bci w hessianie s\u0105 [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-2397","post","type-post","status-publish","format-standard","hentry","category-chem"],"_links":{"self":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/posts\/2397","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/comments?post=2397"}],"version-history":[{"count":2,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/posts\/2397\/revisions"}],"predecessor-version":[{"id":3755,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/posts\/2397\/revisions\/3755"}],"wp:attachment":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/media?parent=2397"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/categories?post=2397"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/tags?post=2397"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}