{"id":3267,"date":"2024-08-01T21:26:53","date_gmt":"2024-08-01T19:26:53","guid":{"rendered":"https:\/\/teneochem.pl\/?page_id=3267"},"modified":"2025-01-30T15:25:23","modified_gmt":"2025-01-30T15:25:23","slug":"mixeny","status":"publish","type":"page","link":"https:\/\/teneochem.pl\/index.php\/mixeny\/","title":{"rendered":"Mixeny"},"content":{"rendered":"\n<p>Nazw\u0119 t\u0119 urobi\u0142em od mieszaniny. Tutaj &#8222;zmieszane&#8221; (skondensowane) s\u0105 fragmenty C[2]karbobeznenu oraz (1<em>Z<\/em>,5<em>Z<\/em>,11<em>Z<\/em>)-cyklotetradeka-1,2,3,5,6,7,11-heptaeno-9,13-diynu:<\/p>\n\n\n\n<figure class=\"wp-block-image aligncenter size-full is-resized\"><img loading=\"lazy\" decoding=\"async\" width=\"428\" height=\"331\" src=\"http:\/\/teneochem.pl\/wp-content\/uploads\/2024\/08\/mixene-kond.jpg\" alt=\"\" class=\"wp-image-3272\" style=\"width:296px;height:auto\" srcset=\"https:\/\/teneochem.pl\/wp-content\/uploads\/2024\/08\/mixene-kond.jpg 428w, https:\/\/teneochem.pl\/wp-content\/uploads\/2024\/08\/mixene-kond-300x232.jpg 300w\" sizes=\"auto, (max-width: 428px) 100vw, 428px\" \/><\/figure>\n\n\n\n<p>Bazuj\u0105c na powy\u017cszej strukturze skonstruowa\u0142em dwa alotropy w\u0119gla C<sub>176<\/sub>. Struktura pierwszego jest zamieszczona poni\u017cej (Orca 6.0.0\/ XTB\/ hess-plus):<\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/nowe2\/mixeny\/mixene-A1-xtb-C176.sdf' data-backgroundcolor='#9911FF' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>W drugim mixenie inaczej po\u0142\u0105czone s\u0105 p\u0142aty (parametry oblicze\u0144 jak wy\u017cej): <\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/nowe2\/mixeny\/mixeneB1-xtb-C176.sdf' data-backgroundcolor='#9911FF' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>Przyznam szczerze, \u017ce po skonstruowaniu alotrop\u00f3w C<sub>176<\/sub> baczniej przyjrza\u0142em si\u0119 strukturze w\u0119glowodoru z pierwszego rysunku. O ile skondensowany fragment C[2]karbobenzenu jest znany, o tyle fragment po prawej stronie (wspomniany ju\u017c (1<em>Z<\/em>,5<em>Z<\/em>,11<em>Z<\/em>)-cyklotetradeka-1,2,3,5,6,7,11-heptaeno-9,13-diyn) mo\u017ce by\u0107 nieznany. By\u0142oby to jednak dziwne bior\u0105c pod uwag\u0119 prostot\u0119 tej cz\u0105steczki. Nie znalaz\u0142em jednak informacji o &#8222;pseudobenzenie&#8221; (tak\u0105 nazw\u0119 nada\u0142em w przyp\u0142ywie zdziwienia) w sieci. Prawdopodobnie niezbyt si\u0119 postara\u0142em. Tym niemniej wykona\u0142em optymalizacj\u0119 tego zwi\u0105zku (Orca 6.0.0\/ revPBE def2-TZVP\/ hess-plus):<\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/nowe2\/mixeny\/pseudobenzen-ov-C14H6.sdf' data-backgroundcolor='#9911FF' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>Gdyby nieznany by\u0142 pseudobenzen, to by\u0107 mo\u017ce sytuacja jest podobna pseudonaftalenem. Wykona\u0142em optymalizacj\u0119 takiego w\u0119glowodoru (parametry oblicze\u0144 jak wy\u017cej):<\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/nowe2\/mixeny\/karbonaftalen1-ov-C26H8.sdf' data-backgroundcolor='#9911FF' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>Istnieje r\u00f3wnie\u017c drugi izomer takiego pseudonaftalenu (parametry oblicze\u0144 jak wy\u017cej):<\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/nowe2\/mixeny\/pseudonaftalen1a-ov-C24H8.sdf' data-backgroundcolor='#9911FF' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>Wreszcie zoptymalizowa\u0142em cz\u0105steczk\u0119 pokazan\u0105 na pocz\u0105tku (parametry oblicze\u0144 jak wy\u017cej). <\/p>\n","protected":false},"excerpt":{"rendered":"<p>Nazw\u0119 t\u0119 urobi\u0142em od mieszaniny. Tutaj &#8222;zmieszane&#8221; (skondensowane) s\u0105 fragmenty C[2]karbobeznenu oraz (1Z,5Z,11Z)-cyklotetradeka-1,2,3,5,6,7,11-heptaeno-9,13-diynu: Bazuj\u0105c na powy\u017cszej strukturze skonstruowa\u0142em dwa alotropy w\u0119gla C176. Struktura pierwszego jest zamieszczona poni\u017cej (Orca 6.0.0\/ XTB\/ hess-plus): W drugim mixenie inaczej po\u0142\u0105czone s\u0105 p\u0142aty (parametry oblicze\u0144 jak wy\u017cej): Przyznam szczerze, \u017ce po skonstruowaniu alotrop\u00f3w C176 baczniej przyjrza\u0142em si\u0119 strukturze w\u0119glowodoru z [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-3267","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages\/3267","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/comments?post=3267"}],"version-history":[{"count":2,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages\/3267\/revisions"}],"predecessor-version":[{"id":3669,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages\/3267\/revisions\/3669"}],"wp:attachment":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/media?parent=3267"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}