{"id":3145,"date":"2024-07-15T16:58:06","date_gmt":"2024-07-15T14:58:06","guid":{"rendered":"https:\/\/teneochem.pl\/?page_id=3145"},"modified":"2025-01-30T15:19:08","modified_gmt":"2025-01-30T15:19:08","slug":"srubeny2","status":"publish","type":"page","link":"https:\/\/teneochem.pl\/index.php\/srubeny2\/","title":{"rendered":"Srubeny2"},"content":{"rendered":"\n<p>Zwi\u0105zek pokazany poni\u017cej posiada \u0142a\u0144cuchy zgi\u0119te, ale nie skr\u0119cone. Oznacza to, \u017ce wszystkie atomy w\u0119gla \u0142a\u0144cuch\u00f3w sprz\u0119\u017conych wi\u0105za\u0144 podw\u00f3jnych le\u017c\u0105 na tej samej p\u0142aszczy\u017anie. Okazuje si\u0119 jednak, \u017ce grupy metylenowe le\u017c\u0105 poza t\u0105 p\u0142aszczyzn\u0105, co generuje chiralno\u015b\u0107 cz\u0105steczki. Jej nazwa systematyczna to (1<em>M<\/em>,11<em>P<\/em>)-cykloeikoza-1,2,3,4,5,6,7,8,11,12,13,14,15,16,17,18-heksadekaen (Orca 5.0.4\/ revPBE\/ def2-TZVP\/ hess-plus):<\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/nowe2\/srubeny\/sruben09-P-onv-C20H8.sdf' data-backgroundcolor='#0033FF' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>Mo\u017cna zauwa\u017cy\u0107, \u017ce grupy metylenowe tworz\u0105 konfiguracj\u0119 kt\u00f3ra przypomina konformacj\u0119 krzes\u0142ow\u0105 w cykloheksanie. Naturalne pytanie o konfiguracj\u0119 analogiczn\u0105 do konformacji \u0142\u00f3dkowej w cykloheksanie nasuwa si\u0119 samo. Nie bada\u0142em tego zwi\u0105zku. Mog\u0119 jedynie powiedzie\u0107, \u017ce taka zmiana konfiguracji zmienia r\u00f3wnie\u017c chiralno\u015b\u0107 na (1<em>M<\/em>, 11<em>M<\/em>).<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Zwi\u0105zek pokazany poni\u017cej posiada \u0142a\u0144cuchy zgi\u0119te, ale nie skr\u0119cone. Oznacza to, \u017ce wszystkie atomy w\u0119gla \u0142a\u0144cuch\u00f3w sprz\u0119\u017conych wi\u0105za\u0144 podw\u00f3jnych le\u017c\u0105 na tej samej p\u0142aszczy\u017anie. Okazuje si\u0119 jednak, \u017ce grupy metylenowe le\u017c\u0105 poza t\u0105 p\u0142aszczyzn\u0105, co generuje chiralno\u015b\u0107 cz\u0105steczki. Jej nazwa systematyczna to (1M,11P)-cykloeikoza-1,2,3,4,5,6,7,8,11,12,13,14,15,16,17,18-heksadekaen (Orca 5.0.4\/ revPBE\/ def2-TZVP\/ hess-plus): Mo\u017cna zauwa\u017cy\u0107, \u017ce grupy metylenowe tworz\u0105 konfiguracj\u0119 [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-3145","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages\/3145","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/comments?post=3145"}],"version-history":[{"count":2,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages\/3145\/revisions"}],"predecessor-version":[{"id":3660,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages\/3145\/revisions\/3660"}],"wp:attachment":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/media?parent=3145"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}