{"id":2932,"date":"2024-06-12T18:11:15","date_gmt":"2024-06-12T16:11:15","guid":{"rendered":"https:\/\/teneochem.pl\/?page_id=2932"},"modified":"2025-01-30T15:11:14","modified_gmt":"2025-01-30T15:11:14","slug":"pirosfery","status":"publish","type":"page","link":"https:\/\/teneochem.pl\/index.php\/pirosfery\/","title":{"rendered":"Pirosfery"},"content":{"rendered":"\n<p>Seria trzech modeli. S\u0105 to pentapodstawione pirole po\u0142\u0105czone ze sob\u0105 za pomoc\u0105 mostk\u00f3w acetylenowych. Modele te o wzorze C<sub>108<\/sub>N<sub>12<\/sub> s\u0105 izomeryczne. Pierwszy z nich pokazuje r\u0119czna animacja poni\u017cej (Orca 4.2.1\/ PM3\/ hess-plus):<\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/nowe2\/pirosfery\/pyr-alfa-pm3C108N12.sdf' data-backgroundcolor='#666699' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>Nast\u0119pni izomer r\u00f3\u017cni si\u0119 od poprzedniego sposobem u\u0142o\u017cenia atom\u00f3w azotu wzgl\u0119dem siebie na sferze (parametry oblicze\u0144 jak wy\u017cej):<\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/nowe2\/pirosfery\/pyr-beta-pm3-C108H12.sdf' data-backgroundcolor='#666699' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>I jeszcze jedne izomer. W tym modelu jedna para atom\u00f3w azotu jest zmostkowana fragmentem etynowym (parametry oblicze\u0144 jak wy\u017cej):<\/p>\n\n\n\n<div style=\"height: 300px; width: 300px; position: relative;\" class='viewer_3Dmoljs' data-href='https:\/\/teneochem.pl\/struct\/nowe2\/pirosfery\/pyr-gamma-pm3-C108N12.sdf' data-backgroundcolor='#666699' data-style='stick:radius~0.2;sphere:radius~0.4'><\/div>\n\n\n\n<p>R\u00f3\u017cnice pomi\u0119dzy pokazanymi modelami nie s\u0105 widoczne bez bardziej szczeg\u00f3\u0142owej analizy geometrii. nie mam czasu na wykonanie tej analizy, gdy\u017c w kolejce czekaj\u0105 kolejne zwi\u0105zki.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Seria trzech modeli. S\u0105 to pentapodstawione pirole po\u0142\u0105czone ze sob\u0105 za pomoc\u0105 mostk\u00f3w acetylenowych. Modele te o wzorze C108N12 s\u0105 izomeryczne. Pierwszy z nich pokazuje r\u0119czna animacja poni\u017cej (Orca 4.2.1\/ PM3\/ hess-plus): Nast\u0119pni izomer r\u00f3\u017cni si\u0119 od poprzedniego sposobem u\u0142o\u017cenia atom\u00f3w azotu wzgl\u0119dem siebie na sferze (parametry oblicze\u0144 jak wy\u017cej): I jeszcze jedne izomer. W [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-2932","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages\/2932","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/comments?post=2932"}],"version-history":[{"count":2,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages\/2932\/revisions"}],"predecessor-version":[{"id":3645,"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/pages\/2932\/revisions\/3645"}],"wp:attachment":[{"href":"https:\/\/teneochem.pl\/index.php\/wp-json\/wp\/v2\/media?parent=2932"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}